Preventing Leaks in PVC Piping
Question: We use a bleach solution to treat cyanide and a caustic solution to raise pH in our wastewater pretreatment system.
Question:
We use a bleach solution to treat cyanide and a caustic solution to raise pH in our wastewater pretreatment system. Ever since this system was installed many years ago, we have been plagued with leaks of the bleach and caustic PVC piping. We have replaced the piping several times and, at best, did not have leakage for 1 yr. Not only is this situation expensive due to lost bleach and caustic and repair costs, we are also very concerned about the safety of our workers. Do you have any suggestions on how we can solve this problem? In a related matter, our PVC ball valves for our caustic feed system also chronically leak. A.H.
Answer:
Bleach or sodium hypochlorite solutions contain some caustic to help stabilize the chlorine. What is happening is that over time the bleach and caustic solutions are dissolving the PVC glue. Many PVC glues contain fumed silica, very small glasslike particles used to thicken the glue. The very high pH of the bleach and caustic solutions dissolve the silica, resulting in leaks.
To ensure leakproof joints, have your piping installers trained and certified in accordance to the American Society for Testing and Materials (ASTM) D2855-96, "Standard practices for making solvent-cemented joints with polyvinyl chloride (PVC) pipe and fittings." A representative from your PVC pipe supplier or manufacturer can provide training. In addition to properly preparing the pipe for joining, there are PVC glues available that do not contain silica and are specifically designed for bleach and caustic service.
For threaded joints, the recommended tape meets military specification, T-27730A. Be sure the joints' threads are clean and sharp.
Regarding your PVC ball valves, check the seal materials. With caustic solutions, we have had better experience with EPDM seals as compared to Viton A. I hope this helps.
Related Content
-
NASF/AESF Foundation Research Project #122: Electrochemical Approaches to Treatment of PFAS in Plating Wastewater - 9th Quarterly Report
The NASF-AESF Foundation Research Board selected a project addressing the problem of PFAS and related chemicals in plating wastewater streams. This report covers the ninth quarter of work (January-March 2023). In this report, we describe our work on evaluating the performance of PFAS degradation by electrooxidation using surface fluorinated Ti4O7 anodes in batch mode.
-
Hubbard-Hall Acquires BioConversion Technology
The acquisition adds experience and biologics to the AquaPure product line.
-
NASF/AESF Foundation Research Project #122: Electrochemical Approaches to Treatment of PFAS in Plating Wastewater - 12th Quarterly Report
This NASF-AESF Foundation research project report covers the 12th quarter of project work (October – December 2023) at the University of Georgia. In our previous report, we described our work on performance and effect of surface fluorinated Ti4O7 anodes on PFAS degradation in reactive electrochemical membrane (REM) mode. This quarter, our experiments involved utilizing porous Ti4O7 plates serving both as anodes and membranes. Tests compared pristine and F-18.6 Ti4O7 anodes at current densities of 10 mA/cm2 and 40 mA/cm2. This 12th quarterly report discusses the mechanisms of the effects on EO performance by anode surface fluorination.